For a 300 Win Mag if you can't get R22 or H4831 to work with 180 to 200gr class bullets, then something is usually wrong with the shooter or with the rifle. That case just loves those powders. I've seen it time and time again. My last 300 Winny I used 72gr R22 with Fed 215 primers shooting 180gr Nosler BTs for a deer load out of a Sendero. That load would group consistantly at 100yds. Probably the best shooting factory hunting rifle I've ever owned.
Then I decided to take it to a registered match one day and shoot it in LG class just to see what it would do. Everything was just as I hunted with except I used an attachment to the front sling swivel to help it semi-ride the bags better and added shims under the rear of the 1 peice base mount to get on paper. I still used my Leupold VX-II 4x-12x scope with the Nosler bullets though.
My first group in competition was 16"?? for 5 shots at 1000yds. And it was all vertical. The group was only about 6 or 7" wide.
Well I adjusted the load and shot it several more times that shooting season. When it was all said and done I had gone to Fed 210s and bumped the load up to 75gr R22 and everything else staying the same. My smallest group that summer was 7.???" for 5 shots from a 100% box stock rifle using hunting bullets and a VarX II 4-12 scope. Sure wish I never sold it.
The moral of the story is the Fed 215 load with 72gr of powder shot great at 100yds and I killed a lot of deer and "stuff" with it at varying ranges. The Fed 210 load with 75gr of powder didn't shoot as good at 100yds but it got rid of the up/down at long range. And I couldn't tell you what the SD was.
The paper told me want I needed to know to make that rifle shoot. When it works on paper the chrono numbers are always there to support the group or else it won't group. But if you concentrate on the spread of the SD, those numbers don't always produce good groups.
So don't get too hung up on SD and chronographs. Work on the load! The primer,powder (type & wgt), and seating depth are where you make your money in load deveolpement. That is 90%+ of the game right there. If you aren't in that 90% bracket all the neck turning, shooting across the chronograph, deburring flash holes, etc, etc is just wasting time and equipment.
Steve