I haven't heard the 25k psi number. ThanksNorma 270 Win brass takes 25,000 psi to fire form decently to 6.5 Sherman with fast pistol powder and COW, with slower powders you won't get it formed as well even at higher pressure, the time to peak definitely changes fire forming, time under the curve does not seem to effect it as much.
I chamber my fire forming barrels for rifles I've chambered at .000 headspace, that lets me basically just neck size with a FL die and not touch the shoulder at that .002 headspace for the case. If I'm making a fire form barrel for something I have not chambered I want fully fire formed brass from it so I can set the fire form chamber to match well for the rifle.