All else being equal, larger contour (CF or steel) will be more stiff and less likely to be affected by any bending in the metal as it heats, though this should be minimal with quality barrel steel and stress relieving. The far greater effect will be from cooking the cartridge in a hot chamber for however many seconds, especially if you're using a temp sensitive powder. See
here among other discussions. A larger steel barrel profile near the chamber will help some with that, and I like that the X-Caliber has a generous shank before the CF starts which should help. But really there's only so much a barrel can do if you're firing a fast string and then pausing to find the next target with a round in the chamber. A temp insensitive powder like H4350 is going to be your best bet in that case (and 25 Creedmoor cartridge case I'd think).