Petey, back in the day.....maybe close to 50 years ago, I was taking apart some old military rounds. They were either .303 British or .50 BMG, memory not what it used be to anymore. The "powder" looked like really thin "angel hair pasta". Any idea what this was and temperature stibility?
Cordite. It was the "powder" in a lot of rounds back in the day. I'm sure it wasn't temp stable, but I've not tested that.
The good temp stable extruded powders we have today are treated with additional chemicals to make them so. There are still quite a few extruded powders that aren't very temp stable. RL-17 is one I had a lot of issue with regarding MV swings as temps changed.
All the Hodgdon Extreme powders come from ADI Thales, in Australia, and those are treated with 2,4 Dinitrotoluene (DNT). It's what gives the powder is pale yellow color as well. It's a burn rate modifier, as well as a water-proofer, and is what I've been lead to believe is specifically what gives their powders better temp stability than others since pretty much no one else uses DNT. It's actually been banned in Europe now and other places.
Diphenylamine is used as well in other powders, as a stabilizer, in double base extruded powders (having both nitrocellulose and nitroglycerin), such as RL-16 for example, that are also treated with diisopentyl phthalate.
The Enduron line uses Centralites as their burn rate modifiers.
RL-16, as an example, is a double base extruded powder. It has both nitrocellulose AND nitroglycerin. Those powders are often referred to as "high energy" powders. That is the reason why you see more speed from RL-16 than you do with H4350, even though the burn rates of the two are similar.
The thing with double base extruded powders though is that they are inherently less temp stable than single base powders. Since RL-16 is specifically treated to be temp stable, it's likely good to go.
I have heard claims that high energy powders tend to erode throats faster, but I can't confirm that. The difference is likely not hugely significant, but the hotter burn and extra energy would have to equate to more firecracking in the throat in a basic physics standpoint. The 500 series of Vihta Vouri powders are also double base extruded, high energy powders.