What was stored in the plastic boxes before you put these cases in? That is such a smooth black corrosion, Not like the Green Gook ammonia, vinegar or certain leather processing chemicals I have dealt with. Looks very much like brass exposed to black powder, Burned black powder or a Sulphur component.
Liver of Sulphur mixed with water is used to age or blacken brass. Sulphur components seems to eat deeper into brass than just the surface.
By chance could those cartridge boxes have at one time held fired Black powder shells like 45-70 Gov..
Or been in the path of a Black Powder spilling, From filling a powder horn or loading Black powder shells.
That may explain why it is just on the neck where they contacted the bottom of the shell box.