Maybe I shouldn't have said 'best ammo', as it's totally possible for ammo with a particular barrel & load to shoot better after it's aged. My contention is that there can be changes, and they could change results. These results would of course need to be validated.
We know there is nothing wrong with fresh ammo, as we load develop with it fresh, and anyone competitive is using it fresh.
I see sized/primed, but unloaded cases drift over time. I've seen many posts over the years with concerns about observed performance changes with aged ammo (>3mos old). And I've seen published reports of ammo creeping in dimensions over time.
I have not personally tested aged ammo -vs- fresh ammo.
It would difficult to prove scientifically, as it would take a long time to do so, and we don't currently have a way to measure neck tension itself. I could test using seating force measure, H20 capacity measurements, and a good chrono and targets, but again, it would take a long time to 'prove' one way or another.