The cooler method doesn't take into account the changes in barrel stiffness or dimension when the temp. changes. I'm killing to 600 yards offhand with my 300 win; good enough for me.
First, if you're killing at 600 yards off-hand, try out for the Olympic team (and take a class in ethics and morals if game is included), especially if you're using a .300 win mag.
Second, what loads are you talking about with the 25WSSM? Factory loads? If so, factory loads commonly have 100fps extreme spreads.
Next, if hand loads, how tightly do you measure case volumes, powder charges, OAL's, neck tension, and what primers do you use. Also, what rifle is it out of? I've used the same ammo out of factory barrels and compared them to custom barrels and the extreme spread in custom barrels has always been much better than factory barrels.
Finaly, the 25 WSSM is very overbore; and I assume you have a 24" barrel, which means a lot of the powder is burning past the muzzle, this has proven to be detrimental in extreme spreads.
Finally, how close is your chronograph to the muzzle? You should place it 15-18' in front of your rifle in order to prevent false readings from the muzzle blast. If you believe that distance is overkill, I encourage you to repeat your tests at 18' from the muzzle, and see how your extreme spread compares. Even with you O35 chronograph.
My two degrees in engineering tell me you need to do a little more homework, you leave a lot to question and from what you say, I buy nothing of it. You seem to be an internet expert, and a very incredible source.
Cheers!