so if i were to shoot a 300 WM and zero it at 100 yards it would not cross the line of sight again at further distances?
Depends on the bullet and caliber. For example, if I zero my 270 Win at 100 yds, the bullet trajectory touches line of of sight just once. If I zero at 200 yds, the bullet crosses line of sight twice, once at about 40 yds and then again at 200 yds.
No, it will not because your 100 yard zero is the second time the bullet crossed the line of sight. The first time it crossed was probably around 75 yards.