Lerch, Like Kirby I have also discovered that the factory new brass often seems to be undersize compared to the chamber dimensions, as an example, I will give you a comparison to yours with several of the 25/06 rifles I have owned.
In 1986 I purchased a new Sako AV 25/06 sporter. The Remington 25/06 new brass measured .464 at the head, .435 at the shoulder, and had a capacity of 65.5 grains.
After firing, full length sized cases were .4675 at head, and .4385 at shoulder, while neck sized cases where .469 at the head, and .4435 at the shoulder. The capacity of fired cases were 68.2 grains. After about 300 shots, the barrel was set back and rechambered to the 25/06 AI, and Remington fireformed cases were .469 at head, .455 at shoulder and had a capacity of 71.2 grains.
Three years ago, I purchased some new brass for a custom 25/06. This time the Remington new brass measured .467 at the head, .439 at the shoulder, and had a capacity of 65.3 grains. The Winchester new brass measured .4665 at the head, .4395 at the shoulder, and had a capacity of 67.6 grains. On this occasion I did not measure the fired head and shoulder dimensions of these cases. However, after about 100 shots the barrel was set back and rechambered to 25/06 AI, and the capacity of the Remington fireformed cases increased to 70.1 grains, and the Winchester cases measured 71.1 grains.
I also endorse Kirby's suggestion of considering rechambering to the 25/06 AI, as my experience in the above 2 rifles suggests that you can expect an increase of about 225 fps with bullets of 100 grains and more. Hope the above information helps. Brian.